![]() MyGolfSpy also confirmed that Performance54 owns 40 percent of Peter Finch’s Finch Golf Media LTD (more than 500,000 YouTube subscribers) and 24.5 percent (not the 49 percent reported by thePNUK) of the Jazzy Golfer. It shows net assets increasing from $119,000 (converted from pounds sterling) in 2019 to more than $827,000 a year later. The company’s balance sheet is also a public record on Companies House. His YouTube channel alone reportedly generates more than $2 million in revenue. Since joining forces with Performance54, Shiels has grown in both reach and reputation. It’s reasonable to presume the partnership agreement was a mutual show of faith by both parties. Its most recent confirmation statement, dated June 28, 2019, shows the same distribution of shares. ![]() Rick Shiels Media Limited was created a year and a half later. The remaining 330 were owned by Performance54. According to documents found in Companies House, Shiels held 670 of the 1,000 shares of that original company. Rick Shiels LTD was incorporated in June 2016. At that time, Shiels was a rising YouTube star with more than 200,000 subscribers. Shiels first signed with Performance54 as a client in 2016. Shiels is YouTube’s most popular golf content creator with more than 2.2 million subscribers, Finch is ranked eighth and The Jazzy Golfer is 149th. MyGolfSpy verified that Performance54 does hold a minority ownership stake in Rick Shiels Media Limited, Peter Finch Golf Media LTD and The Jazzy Golfer. Without either, it would be easy to reach inaccurate-and potentially unfair-conclusions about the relationships between Shiels, Finch and the Jazzy Golfer and the Saudis. It did not, however, include a timeline or context. Through publicly available records, MyGolfSpy was able to confirm that.Īs mentioned, everything in the PNUK video is publicly verifiable and the video itself was substantively accurate. The PNUK video claimed Saudi business interests now own a majority share of Performance54. ![]() The company has offices throughout the Middle East and Asia and opened operations in North America this year. but has become a global golf mover and shaker. Performance54 is relatively unknown in the U.S. Despite that fact, all of the videos were taken down by YouTube following defamation complaints (you can watch an overview here).Īt the center of the web is a company called Performance54.Įstablished in 2015, Performance54 is a high-powered golf-specific public relations, marketing and management firm. Everything in PNUK’s videos was public information and readily verifiable on the Gov.UK Companies House website. The three YouTube/social media personalities named were Rick Shiels, Peter Finch and the Jazzy Golfer, all based in the UK. Several weeks ago, YouTube channel posted a series of videos detailing a spider’s web of connections between three high-profile YouTube golf content creators/influencers and Saudi business interests. Things, as the saying goes, aren’t always what they seem. Our article today is the result of a detailed investigation by MyGolfSpy in an effort to put that story into its proper context. What made the story juicy was an additional connection to three of golf’s leading social media influencers. And that’s the Saudis’ growing interest in recreational golf, golf tourism and the world of golf information and social media.Ī story making the rounds several weeks ago painted a fascinating picture linking the Saudis with a high-powered golf PR firm in the UK. There is another element to this story that’s a little closer to the game of golf that we play. So far, the talk has been about the sport of professional golf. And they have a bottomless well of money to remain so for the long haul. They will be-in fact, already are-a disruptive force in professional golf. Greg Norman and the Saudi backers of LIV are making their intentions clear. That was a DP World Tour event but, if the Tour holds true to its word, none of the LIV jumpers will be welcomed back. A LIV contingent acquitted themselves well in the shortened BMW PGA Championship in the UK this past weekend which, due to the death of Queen Elizabeth, was shortened to 54 holes. Each week brings a new twist, turn, press conference or cast change. The thrust-and-parry between the PGA TOUR and LIV Golf continues unabated. The next time you tee it up with your semi-regular foursome, it’s a fair bet that, by the turn if not before, the conversation will turn to LIV.
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We`ve waited for the suet model to become available and I`m thrilled to say it`s here at last. Sean says: “I`ve been a huge fan of the Squirrel Buster Feeders for decades. ![]() Step 2: After removing the cover, you will notice a yellow center. It will get loose from the other parts and slightly pull it upward, and the cover will take off. For this, push the squirrel feeder towards down and turn it anti-clockwise. With FREE Next-Day Delivery* available, it won’t be long before birds are gratefully dining on this feeder! Follow the step by step guide to apart the feeder: Step 1: First, you need to apart the top of the feeder. If you ever have any questions about the wildlife in your garden, our friendly team are always happy to help, simply contact us on Freephone 08. Stop squirrels stealing bird food with the Squirrel Buster family of totally squirrel proof bird feeders. We are so confident in the quality of the Squirrel Buster™ Feeders that they all come with a lifetime guarantee. Simply adjust the weight mechanism depending on which bird species you want to feed, instructions included. They cannot hang down alongside the feeder and defeat the closing mechanism. Category: Manuals: Perky-Pet® Yellow Petunia Top Fill Glass Hummingbird Feeder 131TF. Cut the refill trips with this tough, high-capacity bird feeder thats totally effective at barring squirrels. Since we all have different budgets and bird feeding preferences, I also have recommendations for a budget, suet, and bird feeder pole to keep the squirrels away. Suet cakes/blocks are protected by the tough steel cage, plus the negative grip tube prevents squirrels from gripping the hanger with their hind legs. ![]() If pesky squirrels keep damaging your bird feeders and stealing the food, Squirrel Busters are what you need. The Squirrel Buster™ Suet Feeder stops squirrels and larger birds accessing two suet feasts/blocks when its` weight activated mechanism drops the shroud cage down. Keep squirrels away from your suet blocks at last! ![]() The development of renewable energy and large-scale energy efficiency requires countries to establish institutional, policy, financial and regulatory frameworks that help attract capital from international financial institutions, and, most importantly, the domestic and international private sector. To become carbon neutral in time to avoid truly catastrophic climate change, we need to replace fossil fuels with a diverse portfolio of renewable sources of energy within the next twelve to 30 years (again, 30 if we start now working on it now, twelve if we don’t). To make the necessary impact in reducing greenhouse gas emissions and providing access to renewable energy, more projects are bigger. Recovery measures are expected to generate new jobs and economic activity. The Covid-19 pandemic is also driving this, so decision makers need to shift their priorities to green recovery rather than unsustainable strategies. Carbon neutral means we aim to reduce and offset GHG emissions to. Today, policymakers and world leaders are gradually seeking a holistic approach to decarbonization, including switching to the use of renewable energy. Toyota is committed to becoming carbon neutral across the vehicle life cycle by 2050. Therefore, as a prelude event to the launching of B20 Indonesia Legacy Program: Carbon Center of Excellence, ICDX together with BNEF will hold a webinar on “Untapping Indonesia Carbon Markets to Accelerate Energy Transition” Related to that, B20 Indonesia Task Force of Trade and Investment and Task Force of Energy, Sustainability, and Climate seek to amplify support to attain greater inclusivity and sustainability to provide businesses with required knowledge to enter or scale up their carbon trading activities. Therefore, it is crucial to ensure industry players have the required knowledge to effectively participate in carbon trading. As Indonesia is currently holding the G20 Presidency, there is no better time than now for Indonesia to actualize its commitment to reduce our greenhouse gas emissions.Ĭarbon trading plays a key role in helping the world reach its net zero pledge by driving investment in greenhouse gas emission mitigation and energy transition measures. ![]() Today, more than 130 countries have now made net zero pledges, covering around 88% of global emissions. ![]() ![]() Most of the hotels are of high quality and attentive to their clients. Playa Flamingo is one of the few remaining places that offer titled, beachfront property, including but not limited to The Palms, Private Residence Club, a titled beachfront luxury development of villas that are located on the south end of Playa Flamingo. The Playa Flamingo real estate market also offers deluxe beachfront villas and condos with ocean views. Some properties even offer their own private, secluded beaches, with access to such beaches through wooden stairs and walkways down the cliffs. Here, you have multi-million-dollar homes built on the cliffs just above Playa Flamingo, each with their own, unique architecture, infinity pool, lush landscaping, and even maids’ quarters. These 360-degree views include views of other popular beaches, including Playa Conchal, Playa Brasilito, Playa Potrero, and Playa La Penca. Playa Flamingo has both a North Ridge and a South Ridge, offering 360-degree views of the Pacific Ocean. The most stunning attribute of Flamingo Beach is its breathtaking oceanfront views. ![]() Known as the Beverly Hills of Costa Rica, Playa Flamingo has served as home to such stars as Linda Carter (known best for her role as Wonder Woman), Elizabeth Taylor, and Richard Burton. Playa Flamingo features a small but attractive town center, complete with hotels, restaurants, shops, a salon, and a pharmacy. Playa Flamingo, or Flamingo Beach, is located in the heart of the Gold Coast Region and in the Guanacaste Province, a province of Costa Rica located in the northwestern part of the country along the coast of the Pacific Ocean. While Costa Rica has many beautiful beaches, few are as stunning as the white sand beaches of Playa Flamingo. With this being World Smile Day, we thought we’d dig into this age-old question.Īccording to dog behaviorists, your dog may indeed be quite happy in this state, but a human-style smile is not the typical way they express joy. ![]() But are they really smiling, or are we projecting human behaviors onto our furry friends? ![]() It sure feels like they are experiencing joy and expressing it in the same way we humans do – with a big grin. When you are playing with your dog or giving them a high-value toy or treat, they often have their mouth open with upturned lips, teeth showing, and tongue lolling.
For acidic amino acids, the isoelectric point will be at lower pH as the acidic side chain will introduce an extra negative charge and for basic amino acids, the isoelectric point will be at higher pH as the basic side chain will introduce an extra positive charge. Asp which was assigned a value of -1.0 at pH 1.8, Lys was assigned. For neutral amino acids, the side chains are neutral and the isoelectric point is given simply by the average of the pK a values of carboxylic acid and amine. complex probably at a position about one-third of the distance. Note: The isoelectric point is given by the average of the pK a values that involve the zwitterions, not just by the pK a values that describe the carboxylic acid group and the amine group. These include Nilakantha Series, Leibniz’s Formula, Ramanujans Pi Formula and other Programming Language specific techniques. (2) At the isoelectric point, the zwitterions form of the amino acid is dominant.Ĭomplete step-by-step answer: If an amino acid has only one amino acid and only one carboxyl group, then the isoelectric point pI is calculated from the mean of the pKas of the amino acid molecule. We have covered different algorithms and approaches to calculate the mathematical constant pi (3.14159.). In this situation, the acidic and basic groups on the amino acids will be ionized.Hint: (1) By isoelectric point we mean the characteristic pH at which net electric charge of a molecule such as amino acid is zero. ![]() Since proteins are biological molecules, they are usually found in a neutral solution that is buffered between pH 7.0 and 7.4. In the following structure, R represents the side chain. You should be familiar with the approximate pKas of the side chains, and the N and C terminal groups. You should be able to identify which side chains contain H bond donors and acceptors. This video shows how to calculate the Taylor polynomial at pi/3 for sin(x) to 5th degree.Taking the derivative of sin(x) 5 times and calculate each value at. After formation of the classes, we calculated the values of pi,j and qk i,j, which are simply positional residue frequencies for the corresponding classes. If you want to calculate Granthams distance by providing the values of the amino acid properties. AsP is made up of 403 amino acid residues with a molecular weight of 42.1kDa (pI 6.51) and its molecular formula was C1859H2930N516O595S4. When the DNTB reaction is performed with serine, there would be no. For the conversion of serine into glycine, serine. The electrophoresis performed at pH 2 would reveal that glycine travels a medium distance. The general structure of an amino acid is shown below. pI calculator for any protein sequence Amino Acid Repository: Properties of Amino Acids Introduction to Amino Acid Reactivity. This pKa value is the closest of all amino acids to physiological pH. The pa of the carboxyl group of serine is 2.21, and the pa of its amino group is 9.15. Calculate the average net charge on serine if it is in a solution that has a pH of 8.50. The amino acid side chains can be classified based on whether they are nonpolar, polar, acidic, or basic. Question: The pa of the carboxyl group of serine is 2.21, and the pa of its amino group is 9.15. ![]() There are 20 amino acids that differ from each other only in the identity of the side chain attached to the alpha-carbon. This means the amino group (NH 2- or NH 3 +-) is attached to the alpha carbon-this is the carbon next to the carboxyl group. There are transport proteins (hemoglobin is an example), storage proteins, structural proteins, proteins for muscular contraction, and others. Proteins that catalyze biological reactions are called enzymes. All proteins are very large molecules with high molecular weights that range from 6500 to 205,000 or more grams per mole.Īn amino acid is a molecule that contains an amino group and a carboxyl group in the same molecule. Amino acids found in proteins are α-amino acids. ![]() Proteins are important biological molecules with many functions. Proteins are polymers of amino acids linked together by peptide bonds. Observe how different amino acids and proteins react in different chemical tests. 2- Calculate the isoelectric point (pI) of each of the following amino acids. a- Histidine b- Aspartic acid c- Serine d- Tyrosine. Hydroxylation of Proline and methylation of Histidine would. Question: 2- Calculate the isoelectric point (pI) of each of the following amino acids. Identify different amino acids and an unknown by paper chromatography. Phosphorylation of Serine, carboxylation of Glutamate, and acetylation of Lysine would lower the pI. \)Įxperiment 72 9 : Qualitative Analysis of Amino Acids and Proteinsĭevelop an understanding of the structure and bonding in amino acids and proteins. ![]() There are more than 80 creatures waiting to be tamed.Īrk: Survival Evolved is also available on PC, PlayStation 4, Xbox One, Android, and iOS. Once tamed, the creature becomes a pet of the player and follows them depending on how well they’ve been tamed and trained. Region Free Ark: Survival Evolved Video Games. If you like and enjoy nosTEAM free games tell all your friends about nosteam.ro - To avoid download unwanted files set your browser to ASK every time where to. To tame a creature, players need to first knock it out and then nurse it back to health. ARK Expansion Map Ragnarok - ARK Expansion Map Primitive+ ARK Total Conversion. One of the game’s main highlights is letting players tame, train, breed, and ride dinosaurs in a living ecosystem. In Ark: Survival Evolved, players are stranded on a mysterious island and must hunt, harvest, craft items, grow crops, and build shelters to survive.
![]() “Sports betting just showed up one day, and everybody knew how to do it, like, we know that purple strain!”) (“I always compare sports betting to cannabis,” Rapinoe joked. Regarding infrastructure, she pointed to strong collective bargaining agreements (and players investing their time and energy to make them as strong as possible) to media rights deals, fan experience, and exploring what sports betting might open up for women’s sports beyond just the financial windfall. While the wins are stacking up and money flows in, Rapinoe said there are still plenty of opportunities to make all this momentum stick and convert into something greater than just sustainability - the long-standing mantra of every women’s sports league.Īsked how to balance the potential of women’s sports with the moment we’re in, Rapinoe answered, “Building the business and infrastructure around the sport because it doesn’t really matter how good a player is or a team is or a moment is or a league is if you don’t have all of the necessary mechanisms.” She said she saw it firsthand when the 2015 World Cup win wasn’t properly harnessed. Clark is standing on the shoulders of Bird and Taurasi and Maya Moore (Rapinoe joked she wasn’t only naming UConn players for the benefit of Bird), Lisa Leslie, and Sheryl Swoopes. Rapinoe stressed time and again on Tuesday that the history of what was built and how it was built, across the landscape of women’s sports, can’t be overlooked even as we celebrate the growth. And when that player does arrive, all the scales and models that say women’s basketball players get only this much-this much airtime, salary, marketing dollars, investment-will be blown to smithereens.” Maybe the Jordan is about to walk through the doors. Fagan’s kicker is prescient: “Taurasi should have been the Jordan, but maybe, just like the league itself, she was ahead of her time. Rapinoe spoke about a 2021 article by Kate Fagan on the WNBA multiple times, which addressed the league’s resilience despite narratives on the quality of play. It’s been there! The WNBA has been around for 28 years, and really doesn’t get the credit as the legacy women’s sports league that all of us are really basing the other leagues off of.” ![]() “Or Sue’s final, when she was in college, had 30,000 people at the game and had five million viewers. “I thought a lot about the national team because it is such a solid foundation and a multi-generational, multi-decade foundation that our team was able to stand upon - and I was able to stand upon - in our fight for equal pay that made it possible to capture a moment,” she said. She pointed to the larger foundation of how women’s sports captured a moment during the 2019 Women’s World Cup win, the 2020 WNBA season in the bubble, and this year’s NCAA finals. And you should do it now, not tomorrow or the next day.”īut for Rapinoe, it didn’t start with the Caitlin Clark effect. This is not just an investment for a mission, or an investment because it’s the right thing. “Whether it’s the funding or VC money coming in, bigger valuations for NWSL clubs, seeing expansion in all the leagues, the PWHL just had the biggest attendance ever - not only the general public, but the business side of things, is all coming together. “It’s something different than everything I’ve been told about it for so long: ‘It’s not exciting.’ That’s obviously not the case. That is more than just capturing a moment and more than just a flash in the pan,” she said. “Eighteen million people watched the final. Beyond Clark’s long-range shooting, and what Rapinoe called “an antidote to always talking about dunking,” was the big picture. The purpose of the panel in New York was to focus on her perspective on the business of women’s sports, and since she had just attended the NCAA Championship between Iowa and South Carolina, we started with her takeaways on the Caitlin Clark effect that has exploded interest in women’s basketball. I feel like it really bodes well for this next phase.” ![]() “I’m just really excited that I’m going to use everything that I learned in my own career, and also the life skills and talents that I had off the field. Instead, Rapinoe has turned her post-retirement attention to embracing a new life as a fan, and her production company that she runs with Bird, A Touch More. The Athletic’s senior writer Meg Linehan interviews Megan Rapinoe. Piranesi was born in Mogliano Veneto, near Treviso, then part of the Republic of Venice. His prints have continued to increase in value to institutions and collectors.Giovanni Battista (also Giambattista) Piranesi (Italian pronunciation: 4 October 1720 – 9 November 1778) was an Italian artist famous for his etchings of Rome and of fictitious and atmospheric "prisons" (Le Carceri d'Invenzione). His dramatic scenes inspired generations of set designers, as well as artists, architects and writers. Piranesi's style greatly influenced the neoclassical art movement of the late 18th century. Piranesi was knighted by the Pope in 1765 and he was elected a Fellow of the Society of Antiquaries in England in 1757. His highly dramatized prints often depict imaginary interiors and frequently include figures in mysterious activities, who are dwarfed by the magnitude of their monumental surroundings. His mission was to glorify the architecture of ancient Rome through his engravings and etchings. After a slow start he eventually achieved great success as an architect, archaeologist, artist, designer, collector, and antiquities dealer. He was the son of a stone mason and was trained as an architect. Piranesi was born in Venice in 1720 and died in Rome in 1778. Many of the antiquities shown in Vasi were eventually sold to King Gustav III of Sweden by Piranesi's son, Francesco Piranesi, after his father’s death, and now reside in the National Museum in Stockholm. Piranesi dedicated many of the plates to patrons, colleagues, good customers and influential people. The plates were eventually published together as a set in 1778 in "Vasi, Candelabri, Cippi, Sarcofagi, Tripodi, Lucerne ed Ornamenti Antichi". In 1768 Piranesi began creating etchings depicting these objects. ![]() Piranesi began collecting, restoring and selling ancient architectural objects in the 1760's in partnership with Thomas Jenkins and Gavin Hamilton, who had financed numerous excavations in the Pantanello area of Hadrian’s Villa at Tivoli. There is a central vertical fold, as issued. The frame measures 28.88" high by 37.25" wide by 1.25" deep. All mounting materials used are archival. It is presented in a brown-colored wood frame and a gray mat. This magnificent etching is printed on heavy laid, chain-linked, deckle edge paper. This Piranesi etching is held by many museums and institutions, including: The Metropolitan Museum, The British Museum, The National Gallery of Art, The Harvard Museum of Art, and The Portland Art Museum. Piranesi's name appears in the lower margin on the right. The peaceful scene is in sharp contrast to the earlier violent battles of the gladiators in this very same spot. Some of these individuals are in casual conversation, like the two men adjacent to the stone slab in the lower left, which contains the title of the piece, one leaning against the structure. People, some ordinary Romans and others possibly tourists on the Grand Tour, wander about the grounds. The casual neglect and disrespect of the local Romans for the Colosseum is further communicated by Piranesi when he includes scenes of animals grazing within the building, fallen blocks of stone laying on the ground and vegetation growing out of portions of the structure. Piranesi chose to jar our senses by selecting a perspective of the Colosseum's interior which places structures in the foreground, like the column of stone in the center and the tall overgrown structure on the right, that disrupt the pleasing symmetrical order of the small archways on the far right. This situation was a motivating factor for him to document the appearance of Rome's ancient architecture with his etchings, before there was further deterioration of these magnificent structures. The way Piranesi chose to illustrate the state of disrepair of the architecture of this wonderful and historically important ancient structure in a way reflects his concern for the decay of many of Rome's monuments and landmarks. This etching depicts the interior of the famous ancient Roman colosseum. ![]() This large framed 18th century etching by Giovanni Battista Piranesi entitled "Veduta dell'interno dell'Anfiteatro Flavio detto il Colosseo" (View of the interior of the Flavian Amphitheater known as the Colosseum), was published in Rome in 1766 in Piranesi's monumental work 'Vedute di Roma' (Views of Rome). Place IP pot back into pressure cooker and replace lid. (if making sweet yogurt, add vanilla now). When milk is at a safe 100 - 105 degrees, add yogurt starter and stir well to incorporate. Then place the pot with milk in the cold water. Place the jars on the rack and secure the lid. I love my Yogourmet, which I bought via Craigslist for about this price. To speed cooling, fill sink or large bowl with ice water. Pour 2 cups of lukewarm water into the Instant Pot and place the wire rack at the bottom. Look for posts on Mondays featuring gluten-free, sugar-free recipes made with healthy plant-based ingredients, Wednesday essays, and Friday giveaways (when available). Today’s post is part of our mission to help you rebuild your health through food and lifestyle choices. If you are using yogurt from a previous batch as the starter, you may find that you need to add a capsule once in a while, as sometimes the culture needs a boost. Don’t think that adding more capsules or starter yogurt will yield thicker yogurt, the culture needs room to grow. If you are not using a yogurt maker, invest in a digital food thermometer until you find a system that works for you. Add the 1 Tablespoon yogurt and mix really well. Probiotic capsules with streptococcus thermophilus yield the thickest yogurt. Just blend the cashews, water and salt in a high speed blender until very smooth. Heat the mixture to 181° F in a glass container set over boiling water. Combine all of the ingredients, except the starter cultures, in a blender and blend on high until smooth. After you soak the cashews, drain and rinse with hot water. Add 1 tablespoon ghee (or oil for vegan), and saute the reserved cashews for 30 seconds. Top with boiling water and let soak for 30 minutes. Notes: If there is colored mold on top when you finish culturing, throw out that batch and start over, making sure your container is super-clean next time. Blend everything till the sauce becomes smooth. ![]() ![]() Electric heating pad with towels on top of it and towels around the container.Warm oven, place culturing container into pan of 110 water, then use lowest setting to maintain that temperature (tricky).Cooler filled with hot water bottles plus your culturing container.Dehydrator (if you can place an item inside).Vegan, gluten-free, low-sodium, reduced-sugar diets |